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Supervised by Ministry of Industry and Information Technology of The People's Republic of China Sponsored by Harbin Institute of Technology Editor-in-chief Yu Zhou ISSNISSN 1005-9113 CNCN 23-1378/T

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Related citation:WANG Ai-jie,ZHOU Ai-juan,WANG Li-yan,LIU Min,CHEN Zhao-bo.Optimization of the operating conditions in a TiO2/Fe3O4-SiO2 photocatalytic reactor for the treatment of industrial wastewater containing Procion Red MX-5B[J].Journal of Harbin Institute Of Technology(New Series),2011,18(2):1-7.DOI:10.11916/j.issn.1005-9113.2011.02.001.
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Optimization of the operating conditions in a TiO2/Fe3O4-SiO2 photocatalytic reactor for the treatment of industrial wastewater containing Procion Red MX-5B
Author NameAffiliation
WANG Ai-jie State Key Laboratory of Urban Water Resource and Environment,Harbin Institute of Technology,Harbin 150090,China
School of Municipal & Environmental Engineering,Harbin Institute of Technology,Harbin 150090,China 
ZHOU Ai-juan School of Municipal & Environmental Engineering,Harbin Institute of Technology,Harbin 150090,China 
WANG Li-yan School of Municipal & Environmental Engineering,Harbin Institute of Technology,Harbin 150090,China 
LIU Min School of Chemistry & Chemical Engineering,Harbin Normal University,Harbin 150025,China 
CHEN Zhao-bo State Key Laboratory of Urban Water Resource and Environment,Harbin Institute of Technology,Harbin 150090,China 
Abstract:
According to the design principle of the central composite experimental,the method of response surface analysis with three factors and three levels was adopted based on one factor test.A second-order quadratic equation for photocatalysis of Procion Red MX-5B was built.Response surface and contour were graphed with the decoloration rate of Procion Red MX-5B as the response value.Based on the analysis of the response surface plots and their corresponding contour plots,effects of pH value,irradiation time and catalyst loading were explored.By using this new method,the optimum decoloration condition was obtained as follows:pH value,1.3;irradiation time,49.9 min;catalyst loading,0.57 g/L.In the optimization,R-Squared and Adj R-Squared correlation coefficients for quadratic model were evaluated quite satisfactorily as 0.9310 and 0.8620,respectively.Under the optimum conditions established,the performance of 99.47% for color removal was experimentally reached.It was found that all factors considered have an important effect on the decolorization efficiency of Procion Red MX-5B.By the ANOVA analysis and model confirmation the optimal solution obtained using RSM was experimentally validated and credible with preferable instructional ability for experiments.
Key words:  TiO2/Fe3O4-SiO2 photocatalyst  response surface methodology(RSM)  optimization of decoloration condition
DOI:10.11916/j.issn.1005-9113.2011.02.001
Clc Number:X703
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