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主管单位 中华人民共和国
工业和信息化部
主办单位 中国材料研究学会
哈尔滨工业大学
主编 苑世剑 国际刊号ISSN 1005-0299 国内刊号CN 23-1345/TB

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引用本文:汪明球,闫军,崔海萍,杜仕国.氧化铝粉体表面纳米化修饰及其在耐磨涂层中的应用[J].材料科学与工艺,2013,21(1):123-128.DOI:10.11951/j.issn.1005-0299.20130122.
WANG Ming-qiu,YAN Jun,CUI Hai-ping,DU Shi-guo.Surface modification of Al2O3 powders and its application in wear-resistant coatings[J].Materials Science and Technology,2013,21(1):123-128.DOI:10.11951/j.issn.1005-0299.20130122.
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氧化铝粉体表面纳米化修饰及其在耐磨涂层中的应用
汪明球1,闫军1,崔海萍2,杜仕国1
(1.军械工程学院 三系,河北 石家庄 050003;2.军械工程学院 基础部,河北 石家庄 050003)
摘要:
在低温条件(80℃)下,以钛酸丁酯为原料,利用胶溶–回流法在氧化铝粉体表面制备了纳米TiO2颗粒.通过扫描电镜、X射线衍射、X光电子能谱仪、BET等检测手段对复合颗粒的表面形貌、包覆层相组成、比表面积等进行了表征.结果表明,纳米TiO2颗粒在微粉表面形成纳米薄膜修饰层,包覆层主要为锐钛矿型相,表面纳米化修饰后氧化铝粉体表面的粗糙度显著增加,比表面积较包覆前提高了30倍以上.将经表面纳米化修饰后的微粉应用于以有机硅改性环氧树脂为基体的耐磨涂层中,其磨损失重仅为包覆前复合耐磨涂层的55%,耐磨性显著提高,并初步讨论了复合耐磨涂层的摩擦磨损性能.
关键词:  复合颗粒  纳米TiO2  表面纳米化修饰  耐磨
DOI:10.11951/j.issn.1005-0299.20130122
分类号:
基金项目:国家自然科学基金(50572122);军械工程学院基础部科研基金(JCB1006).
Surface modification of Al2O3 powders and its application in wear-resistant coatings
WANG Ming-qiu 1,YAN Jun 1,CUI Hai-ping 2,DU Shi-guo 1
(1.The3rd Department,Ordnance Engineering College,Shijiazhuang 050003,China; ;2.Physics and Chemistry Section,Ordnance Engineering College,Shijiazhuang 050003,China)
Abstract:
By using tetrabutyl titanate as the main material,nano-TiO2/Al2O3 composite particles in acidic abundant aqueous solution was prepared by the peptization and reflux method at low temperature(80℃).The properties of composite particles,including surface morphology,the phase composition of the coating layer,specific surface area,were characterized by SEM,XRD,XPS,BET.The results show that the TiO2 nanoparticles in coating layer of which the main phase was anatase,coated on the Al2O3 powders uniformly and discretely.The surfaces of particles were more rough after coating,the value of specific surface area of the composite particles was elevated by over 30times than that before coating.Compared with uncoated Al2O3 powders as filler,the abrasive loss of composite coatings decreased to 55percent of that coatings filled with uncoated Al2O3 powders,when the composite particles were filled in wear-resistant coatings based on the silicone modified epoxy resins.Finally,the wear properties of wear-resistance coatings was discussed preliminarily.
Key words:  composite particles  nano-TiO2  surface modification  wear-resistance

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