磁性生物炭去除水中抗生素的研究进展
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(1.黑龙江大学 建筑工程学院,哈尔滨 150060;2.哈尔滨工业大学 环境学院,哈尔滨 150090)

作者简介:

秦可娜(1989—),女,博士,副教授;魏亮亮(1985—),男,教授,博士生导师

通讯作者:

魏亮亮,weill333@163.com

中图分类号:

X52

基金项目:

国家自然科学基金(22206048);黑龙江博士后基金面上项目(LBH-Z22239);黑龙江省自然科学基金(LH2024E110)


Research progress on magnetic biochar for removal of antibiotics from water
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(1.School of Civil Engineering, Heilongjiang University, Harbin 150060, China; 2.School of Environment, Harbin Institute of Technology, Harbin 150090, China)

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    摘要:

    近年来,抗生素引起的水体污染问题备受关注,磁性生物炭作为一种新型吸附材料,因孔隙发达、比表面积大、官能团丰富且易于回收,在去除水中抗生素方面具有巨大潜力。本文概括了磁性生物炭与普通生物炭相比的典型特点;总结了热解法、共沉淀法、水热法、球磨法制备磁性生物炭的原理,对比不同方法需要关注的关键制备条件,发现除了控制温度、制备时间、磁性材料与生物炭配比外,还可通过添加改性试剂或研磨试剂的方法进一步提高磁性生物炭对抗生素的吸附能力;分析了磁性生物炭吸附抗生素的作用机制,包括孔隙填充、π—π共轭作用、络合作用、静电作用等,阐明了磁性材料在吸附过程中起到的作用,并对如何优化和改良磁性生物炭的性能进行了探讨;梳理了磁性生物炭与其他水处理工艺如光催化、芬顿等耦合的研究进展。最后,对磁性生物炭未来的研究方向和应用前景进行了展望,为优化设计磁性生物炭、强化水中抗生素的去除提供了方向。

    Abstract:

    Recently, there has been a significant focus on the issue of antibiotic pollution in water bodies. As a novel adsorbent material, magnetic biochar exhibits excellent potential for antibiotic removal due to its exceptional porosity, extensive surface area, abundant functional groups, and ease of recovery. This paper outlines the typical characteristics of magnetic biochar compared to conventional biochar. It summarizes the principles of various preparation methods, including pyrolysis, coprecipitation, hydrothermal synthesis, and ball milling, while comparing the crucial preparation conditions that must be considered for each method. In addition to controlling temperature, preparation time, and the ratio of magnetic material to biochar, further modifications with different reagents are discussed as potential means to enhance antibiotic adsorption capacity. The paper provides a detailed analysis of adsorption mechanisms such as pore filling, π—π conjugation, complexation, and electrostatic interactions, elucidating magnetic materials′ role during adsorption. Furthermore, the study reviews the recent progress in coupling magnetic biochar with other water treatment methods, such as photocatalysis and Fenton reactions. Finally, the paper outlines future research directions and application prospects for magnetic biochar, providing guidance for optimizing its design and enhancing the removal efficacy of antibiotic from water treatment.

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秦可娜,毕研珂,朱佳琪,韩克强,张多英,魏亮亮,贺馥.磁性生物炭去除水中抗生素的研究进展[J].哈尔滨工业大学学报,2025,57(10):21. DOI:10.11918/202409076

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  • 收稿日期:2024-09-27
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  • 在线发布日期: 2025-09-29
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