| 引用本文: | 陈振宁,赵慨,吴晓宏,王艳萍.染料敏化太阳能电池中凝胶电解质的研究[J].材料科学与工艺,2011,19(1):95-98.DOI:10.11951/j.issn.1005-0299.20110119. |
| CHEN Zhen-ning,ZHAO Kai,WU Xiao-hong,WANG Yan-ping.Study on the the composition of gel polymer electrolyte for dye-sensitized solar cells[J].Materials Science and Technology,2011,19(1):95-98.DOI:10.11951/j.issn.1005-0299.20110119. |
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| 摘要: |
| 为提高染料敏化太阳能电池中电解液的稳定性,对凝胶电解质进行了研究.以1,2-二1甲基-3-丙基咪唑碘(DMPII)作为I-源,以3-甲氧基丙腈作为溶剂,以偏四氟乙烯-六氟丙烯聚合物(P(VDF-HFP))作为胶凝剂,N-甲基苯并咪唑作为添加剂,制备了凝胶电解质.结果表明,随着电解质中DMPII量及碘量的增加,染料敏化太阳能电池的光电转化效率呈现先增大后降低的趋势.当P(VDF-HFP)的质量分数为5%、DMPII及I2的浓度分别为0.8 mol/L及0.04 mol/L时,制备的凝胶电解质染料敏化太阳能电池光电转化效率最高,在100 mW/cm2的模拟太阳光照射下取得开路电压0.703 V,短路电流密度11.81 mA/cm2,填充因子0.618,总的光电转换效率5.13%. |
| 关键词: 染料敏化太阳能电池 凝胶电解质 1,2-二甲基-3-丙基咪唑碘 光电转化效率 |
| DOI：10.11951/j.issn.1005-0299.20110119 |
| 分类号:TM914.4 |
| 基金项目:国家自然科学基金资助项目(50702018,51078101);表面工程技术国家级重点实验室基金资助项目(9140C5401040702);新世纪优秀人才计划资助项目(NCET-09-0064);黑龙江省自然科学基金资助项目(B2007-04) |
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| Study on the the composition of gel polymer electrolyte for dye-sensitized solar cells |
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CHEN Zhen-ning1, ZHAO Kai2, WU Xiao-hong1, WANG Yan-ping1
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1.Department of Chemistry,Harbin Institute of Technology,Harbin 150001,China;2.National Key Laboratory of Surface Engineering,Lanzhou Institute of Physics,Lanzhou 730000,China
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| Abstract: |
| To improve the stability of electrolyte for dye-sensitized solar cells,the gel polymer electrolyte was studied.Poly(vinylidenefluoride-co-hexafluiripripylene)(P(VDF-HFP)) was employed to solidify 3-methoxypropionitrile based liquid electrolytes containing 1,2-dimethyl-3-propylimidazolium iodide(DMPII) and 1-methylbenzimidazole as iodide resource and addition respectively.The results showed that the ionic conductivity decreased with the increasing of P(VDF-HFP),and the conversion efficiency of the dye-sensitized solar cell increased first,and then deceased with the increase of DMPII and I2.When ionic electrolyte composed of 0.8 mol/L DMPII,0.04 mol/L I2,0.1mol/LLiI,0.2 mol/L 1-methylbenzimidazole and 5% P(VDF-HFP) a short circuit photocurrent density of 11.81 mA/cm2,an open circuit voltage of 0.703 V,a fill factor of 0.618 and an overall conversion efficiency of 5.13% under AM irradiation(100 mW/cm2) were observed. |
| Key words: dye-sensitized solar cells gel polymer electrolyte imidazolinium iodides P(VDF-HFP) conversion efficiency |
