| 引用本文: | 丁宏升,张永,姜三勇,陈瑞润,郭景杰.稳恒电场对小晶面晶体生长的影响[J].材料科学与工艺,2011,19(2):144-148.DOI:10.11951/j.issn.1005-0299.20110230. |
| DING Hong-sheng,ZHANG Yong,JIANG San-yong,CHEN Rui-run,GUO Jing-jie.Effects of steady electric field on faceted crystal growth[J].Materials Science and Technology,2011,19(2):144-148.DOI:10.11951/j.issn.1005-0299.20110230. |
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| 摘要: |
| 本文选用NH4Cl和H2O过饱和二元溶体为研究对象,研究其在稳恒电场作用下溶体中游离晶的重熔规律及晶体生长规律.利用显微镜感光器件(CCD)及智能通讯测温仪表,对实验过程进行实时照片拍摄和实时温度记录.结果表明:电场的Joule Heat效应为决定性因素,使得NH4Cl溶体温度场显著变化,导致糊状区的游离晶重熔明显;NH4Cl在凝固时会自然形成电阻梯度,当在垂直于NH4Cl晶体的凝固方向上施加外加电场时,Joule热可造成附加的温度梯度,温度梯度方向与原溶体的正温度梯度方向一致,电场加载后会提高溶体的温度梯度,有利于促进固液界面的稳定性. |
| 关键词: 小晶面晶体 NH4Cl 稳恒电场 晶体生长 |
| DOI：10.11951/j.issn.1005-0299.20110230 |
| 分类号:TB302 |
| 基金项目:教育部新世纪优秀人才支持计划资助项目(NCET-08-0164) |
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| Effects of steady electric field on faceted crystal growth |
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DING Hong-sheng1, ZHANG Yong1, JIANG San-yong2, CHEN Rui-run1, GUO Jing-jie1
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1.School of Materials Science and Engineering,Harbin Institute of Technology,Harbin 150001,China;2.School of Electrical Engineering and Automation,Harbin Institute of Technology,Harbin 150001,China
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| Abstract: |
| A binary supersaturated solution of NH4Cl and H2O was selected to investigate the remelting of free faceted NH4Cl crystals in mushy zone under a steady electric field and the influence of the electric field on crystal growth.The Charge Coupled Device(CCD) in microscope and a temperature instrument with communication to computer were utilized to snap the real time profile of crystals and record the temperature data respectively.Experimental results show that the thermal field of the solution is affected significantly by Joule Heat,which leads to the consequent remelting of free crystals in mushy zone.When NH4Cl is solidifying,there is an electrical resistance gradient to emerge which will result in an extra thermal gradient whose direction agrees with that of the original positive gradient.It implies that application of electric field will intensify the thermal gradient in the binary solution,which conduces to the stabilization of solid/liquid interface. |
| Key words: faceted crystals NH4Cl stable electric field crystal growth |
