| 引用本文: | 吕宏飞,李锦书,白雪峰.Mn2+掺杂多孔CdIn2S4光催化剂的制备及催化制氢性能[J].材料科学与工艺,2011,19(6):138-142.DOI:10.11951/j.issn.1005-0299.20110625. |
| Lü Hong-fei,LI Jin-shu,BAI Xue-feng.Synthesis and photocatalytic hydrogen production property over Mn2+ doped porous CdIn2S4 photocatalyst under visible light irradiation[J].Materials Science and Technology,2011,19(6):138-142.DOI:10.11951/j.issn.1005-0299.20110625. |
|
| 摘要: |
| 为提高光催化剂的比表面积,以十二烷基磺酸钠(SDS)为模板剂,采用水热法制备出系列Mn2+掺杂的CdIn2S4多孔光催化剂.通过XRD、FESEM、UV-Vis、XPS等分析手段对催化剂进行了表征,考察了掺杂Mn2+浓度对多孔CdIn2S4光催剂的形貌结构和可见光催化产氢性能的影响.结果表明,Mn2+掺杂影响催化剂的晶体结构及其微观形貌,掺杂后的CdIn2S4光催化剂产氢活性显著提高,其中Mn2+(0.7%)-CdIn2S4光催化剂表现出最优产氢活性,产氢速率达到1296.2μmol/(h.g). |
| 关键词: 多孔CdIn2S4 Mn2+掺杂 光催化 水热合成 |
| DOI：10.11951/j.issn.1005-0299.20110625 |
| 分类号: |
| 基金项目:国家高技术研究发展计划资助项目(2007AA03z337);黑龙江省杰出青年基金资助项目(JC200615) |
|
| Synthesis and photocatalytic hydrogen production property over Mn2+ doped porous CdIn2S4 photocatalyst under visible light irradiation |
|
Lü Hong-fei1,2, LI Jin-shu3, BAI Xue-feng1,2
|
|
1..School of Chemical and Environmental Engineering,Harbin University of Science and Technology,Harbin 150040,China;2.Institute of Petrochemistry,Heilongjiang Academy of Sciences, Harbin 150040,China;3.School of Chemistry & Materials,Heilongjiang University,Harbin 150080,China
|
| Abstract: |
| To improve the specific surface area of photocatalysts,a series of Mn2+ doped porous CdIn2S4 photocatalysts with good optical property were synthesized via a facile hydrothermal process using sodium dodecyl sulfate(SDS) as template.The above-prepared photocatalysts were characterized by X-ray diffraction(XRD),field emission scanning electron microscopy(FESEM),UV-Vis diffusive reflectance spectroscopy(DRS) and X-ray photoelectron spectroscopy(XPS),and the influences of concentration of Mn2+doping on the morphology and photocatalytic activity of CdIn2S4photocatalysts were investigated.The results demonstrated that Mn2+ doping had great effects on the crystal structure and micro-morphology.The photocatalytic activity of CdIn2S4was enhanced by Mn2+ doping,and the highest rate of hydrogen evolution of 1296.2 μmol/(h·g) over Mn2+(0.7%)-CdIn2S4 was observed. |
| Key words: porous CdIn2S4 Mn2+ doping photocatalyze hydrothermal synthesis |
