引用本文: | 袁浩,马成勇,齐彦昌,李莉,崔冰.690镍基合金焊条熔敷金属的组织与性能研究[J].材料科学与工艺,2016,24(2):41-46.DOI:10.11951/j.issn.1005-0299.20160204. |
| YUAN Hao,MA Chengyong,QI Yanchang,LI Li,CUI Bing.Research of the microstructure and properties of ENiCrFe-7 weldments[J].Materials Science and Technology,2016,24(2):41-46.DOI:10.11951/j.issn.1005-0299.20160204. |
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690镍基合金焊条熔敷金属的组织与性能研究 |
袁浩1,2,马成勇2,齐彦昌2,李莉1,崔冰1,2
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(1.昆明理工大学 材料科学与工程学院,昆明 650093;2.先进钢铁流程及材料国家重点实验室(钢铁研究总院),北京100081)
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摘要: |
采用金相显微镜、扫描电镜、拉伸试验、弯曲试验和晶间腐蚀试验分析了690镍基合金ENiCrFe-7焊条中各元素对熔敷金属组织、缺陷和力学性能的影响,研制符合核电设备使用要求的焊条.研究表明:焊缝熔敷金属中的沿晶裂纹引起焊缝金属拉伸性能、冲击韧性和弯曲性能的降低;随着焊缝中Nb,Ti元素含量的增加,焊缝析出相(Nb,Ti)(C,N)和NbC的数量增加,焊缝中滑移晶界受到析出相的钉扎,裂纹扩展受到抑制,焊缝熔敷金属的强度、塑性和弯曲性能得到提高;Nb和Ti的加入减小了Cr23C6析出数量,抑制了晶间腐蚀裂纹的产生.新研制的镍基焊条满足核电设备对焊缝熔敷金属的性能要求.
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关键词: 焊条 沿晶裂纹 析出相 晶间腐蚀 力学性能 |
DOI:10.11951/j.issn.1005-0299.20160204 |
分类号:TG422.1 |
文献标识码:A |
基金项目:国家高技术研究发展计划资助项目(2007AA03Z506). |
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Research of the microstructure and properties of ENiCrFe-7 weldments |
YUAN Hao1,2,MA Chengyong2,QI Yanchang 2,LI Li1,CUI Bing1,2
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(1.Kunming University of Science and Technology,College of Materials Science and Engineering,Kunming 650093,China; 2. State Key Laboratory of Advanced Steel Process and Products(Central Iron and Steel Research Institute),Beijing 100081,China)
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Abstract: |
In order to develop the welding electrodes and meet the requirement for the key components of nuclear power plant,the influence of ENiCrFe-7 welding electrodes compositionon the microstructure and mechanical properties of Ni-based weldments have been analyzed using optical microscopy, scanning electron microscopy, tensile test, bending test and intergranular corrosion test. The results showed that intergranular cracks caused the degradation of tensile strength, impact energy and bending property of weld metal. The addition of Nb and Ti can form MX (M=Nb,Ti,X=C) precipitates, which were present to “pin” grain boundary motion and impede the propagation of cracks. The precipitates increased with the increase of Nb and Ti contents in the weld metals. The addition of Nb and Ti can improve the tensile strength, plasticity and bending property of the weld metals. The addition of Nb and Ti can fix C in grain, decrease the number of Cr23C6, which is helpful for minimizing intergranular corrosion of the weld. The self-made electrode had good comprehensive property which could meet the requirements for the key components of nuclear power plant.
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Key words: electrode intergranular crack precipitate intergranular corrosion mechanical property |