| 引用本文: | 胡玉龙,孙玥,赵蕾,方喆禹,金星,冉松林.回收利用光伏产业中金刚线切割废料的研究进展[J].材料科学与工艺,2025,33(4):81-96.DOI:10.11951/j.issn.1005-0299.20240087. |
| HU Yulong,SUN Yue,ZHAO Lei,FANG Zheyu,JIN Xing,RAN Songlin.Research progress on recycling of diamond-wire sawing silicon waste in photovoltaic industry[J].Materials Science and Technology,2025,33(4):81-96.DOI:10.11951/j.issn.1005-0299.20240087. |
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| 摘要: |
| 在“双碳”大背景下,光伏产业成为了国家重点发展行业。但是在利用金刚线切割技术生产太阳能电池的核心原料——晶硅片时,会产生大量的切割废料,即金刚线切割废料。金刚线切割废料是一种富含纯硅的亚微米级薄片状物质,如果不加以利用,会造成环境污染和资源浪费,因此该废料的回收利用成为当下研究的热点。目前,金刚线切割废料的回收利用方式主要为制备纯硅、陶瓷材料、电极材料和硅基合金。除此之外,还有利用金刚线切割废料制备析氢产氢材料、吸附剂材料、金属捕收剂等回收方式。本综述首先阐述了金刚线切割废料的物化特性,然后对其回收利用的研究展开了详细介绍,最后对其回收利用的技术做出了总结和展望,为光伏产业中金刚线切割废料的回收利用提供了一定的参考和启示。 |
| 关键词: 金刚线切割废料 纯硅 陶瓷 电极材料 硅基合金 |
| DOI：10.11951/j.issn.1005-0299.20240087 |
| 分类号:X705 |
| 文献标识码:A |
| 基金项目:国家自然科学基金青年基金资助项目(52304417)；安徽省自然科学基金青年项目(2208085QE146)；安徽省自然科学基金重点项目(KJ2021A0405). |
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| Research progress on recycling of diamond-wire sawing silicon waste in photovoltaic industry |
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HU Yulong1, SUN Yue1, ZHAO Lei1, FANG Zheyu1, JIN Xing1, RAN Songlin2
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(1.Key Laboratory of Metallurgical Emission Reduction & Resources Recycling(Anhui University of Technology), Ministry of Education, Ma anshan 243000, China; 2.School of Materials Science and Engineering, Anhui University of Technology, Maanshan 243000, China)
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| Abstract: |
| In the context of the “Carbon Peaking and Carbon Neutrality” strategy, the photovoltaic industry has become a key industry in China. However, when utilizing diamond-wire sawing method to produce crystalline silicon wafers (the raw material for solar cells), the slicing process produced a large amount of sawing waste, i.e. diamond-wire sawing silicon waste (DWSSW). DWSSW is in the form of submicron flakes rich in pure silicon. If not utilized, this waste can pose a significant environmental hazard and resource wastage, making its recycling a current focus of research. Currently, the recycling and utilization of DWSSW primarily involves the preparation of pure silicon, ceramic materials, electrode materials, and silicon-based alloys. In addition, there are some non-mainstream studies, such as the preparation of hydrogen evolution materials, adsorbents, and metal collectors. In this review, the physical and chemical characteristics of DWSSW were firstly introduced, followed by a detailed analysis of the studies on its recycling and utilization. Finally, a summary and outlook on the studies were proposed,providing insights and references for the recycling and utilization of DWSSW in photovoltaic industry. |
| Key words: diamond-wire sawing silicon waste pure silicon ceramics electrode materials alloys |
