引用本文: | 姜雨辰,唐玮,彭玉兴.纳米CaB/MoDDP复合润滑油添加剂的摩擦学性能[J].哈尔滨工业大学学报,2022,54(7):111.DOI:10.11918/202112017 |
| JIANG Yuchen,TANG Wei,PENG Yuxing.Tribological performance of nano CaB/MoDDP compound lubricant additive[J].Journal of Harbin Institute of Technology,2022,54(7):111.DOI:10.11918/202112017 |
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摘要: |
为提高润滑油的抗磨减摩性能,提升机械设备在恶劣工况下运行的稳定性和安全性,通过四球机和低速重载摩擦磨损试验机研究纳米硼酸钙(CaB)和二烷基二硫代磷酸钼(MoDDP)复合润滑油添加剂的减摩抗磨性能,期望取得较单一添加剂更优异的润滑效果。研究结果显示:制备的纳米CaB为不规则的纳米薄片状,平均尺寸为50~150 nm,经油酸改性后在基础油中具有良好的分散稳定性;纳米CaB和MoDDP均可显著提高润滑油的润滑效果,随着纳米CaB和MoDDP添加质量分数的增加,摩擦因数和磨斑直径呈现先降低后升高的趋势,纳米CaB和MoDDP的最佳添加质量分数分别为2.0%和1.5%;与单一添加CaB、MoDDP相比,复合CaB/MoDDP可进一步改善润滑油的减摩抗磨性能,MoDDP和CaB的最佳质量配比为1.5%∶3.0%,此时摩擦副的摩擦因数最小,磨痕最浅,磨斑直径最小,最大无卡咬负荷最高,并且在低速重载工况下,显示出优良的润滑效果,表明CaB/MoDDP复合润滑油添加剂具有良好的减摩抗磨效果,可以显著提高润滑油的性能。 |
关键词: 纳米硼酸钙 二烷基二硫代磷酸钼 复合润滑油添加剂 抗磨减摩 低速重载 |
DOI:10.11918/202112017 |
分类号:TH117.1 |
文献标识码:A |
基金项目:江苏省高校优势学科建设工程项目(PAPD No.48) |
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Tribological performance of nano CaB/MoDDP compound lubricant additive |
JIANG Yuchen,TANG Wei,PENG Yuxing
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(School of Mechatronic Engineering, China University of Mining and Technology, Xuzhou 221116, Jiangsu, China)
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Abstract: |
To improve the tribological properties of lubricant oil and enhance the stability and security of mechanical equipment under severe working conditions, the friction reduction and anti-wear performance of nano-calcium borate (CaB) and molybdenum dialalkyl dithiophosphates (MoDDP) composite additives were studied using four-ball tester and block on ring tester. The results showed that the prepared nano-CaB was a nanosheet with irregular shape and the average size was 50-150 nm. After oleic acid modification, it showed good dispersion stability in base oil. Both nano-CaB and MoDDP could significantly improve the lubrication effect of lubricant oil. With the increasing of nano-CaB and MoDDP mass fraction, the friction coefficient and grinding spot diameter firstly decreased and then increased. The optimal adding mass fraction of nano-CaB and MoDDP was 2.0% and 1.5%, respectively. Compared with single addition of CaB and MoDDP, compound CaB/MoDDP could further improve the friction reducing and anti-wear performance of lubricant oil. The optimal mass fraction ratio of MoDDP and CaB is 1.5%∶3.0% that showed the smallest friction coefficient and grinding spot diameter, and the highest maximum nonseizure load. It also showed excellent lubrication effect under low speed and heavy load condition. |
Key words: nano-calcium borate MoDDP composite lubricant additives friction reduction and anti-wear performance low speed and heavy load |