| 引用本文: | 杨海洋,杜星,甘振东,李圭白,梁恒.混凝-助凝-超滤工艺处理地表水膜污染[J].哈尔滨工业大学学报,2017,49(2):13.DOI:10.11918/j.issn.0367-6234.2017.02.003 |
| YANG Haiyang,DU Xing,GAN Zhendong,LI Guibai,LIANG Heng.Membrane fouling on coagulation/aid-coagulation/ultrafiltration process for drinking water treatment[J].Journal of Harbin Institute of Technology,2017,49(2):13.DOI:10.11918/j.issn.0367-6234.2017.02.003 |
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| 摘要: |
| 为考查混凝剂种类对混凝-助凝-超滤工艺处理较高浊度地表水时膜污染的影响，采用动态测絮体粒径的马尔文粒度仪和微型超滤系统研究聚合氯化铝(PACl)和三氯化铁(FeCl3)与助凝剂聚丙烯酰胺(PAM)联用形成的絮体对超滤膜污染的影响.结果表明，固定混凝剂投量(PACl和FeCl3为3 mg/L)，当PAM投量在0~0.4 mg/L时，絮体粒径增至1 000 μm，相对于单一投加PACl (3~370 μm)和FeCl3(360~420 μm)时增长明显，且随投量增加比通量增大(PACl:0.56~0.64;FeCl3:0.71~0.76)、滤饼层阻力减小(PACl:由0.90×10-11降至0.52×10-11 m-1; FeCl3:由0.47×10-11降至0.28×10-11 m-1)；然而当PAM投量增大为1.0 mg/L时，比通量明显减小至0.48，而滤饼层阻力显著增加至1.55×10-11m-1.因此，助凝剂PAM存在最优投量(0.4 mg/L)膜污染最小.结合纳米粒度仪和扫描电镜证明滤饼是主要污染机理，但膜孔堵塞在PAM投量高时明显.
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| 关键词: 聚合氯化铝 三氯化铁 聚丙烯酰胺 超滤 膜污染 |
| DOI：10.11918/j.issn.0367-6234.2017.02.003 |
| 分类号:X703 |
| 文献标识码:A |
| 基金项目:国家自然科学基金优青项目(51522804)；新世纪优秀人才支持计划(NCET-13-0169) |
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| Membrane fouling on coagulation/aid-coagulation/ultrafiltration process for drinking water treatment |
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YANG Haiyang, DU Xing, GAN Zhendong, LI Guibai, LIANG Heng
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(State Key Laboratory of Urban Water Resource and Environment (Harbin Institute of Technology), Harbin 150090, China)
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| Abstract: |
| To examine the effects of different coagulants on membrane fouling in the coagulation/aid-coagulation/ultrafiltration process for high turbidity surface water purification, Malvern laser particle size analyzer and micro-scale ultrafiltration unit were used to investigate membrane fouling caused by the flocs formed by coagulants (i.e. aluminium polychlorid (PACl), ferric trichloride (FeCl3)) and aid-coagulant (polyacrylamide (PAM)). The results indicated that, with the constant dosage of combined coagulants (PACl=FeCl3=3 mg/L), the PAM dosage of 0-0.4 mg/L rendered the d50 of flocs exhibited an obvious increase (eventually reached to 1 000 μm) compared to those with single coagulant dosage of PACl (3-370 μm) or FeCl3(360-420 μm). With the dosage of PAM increased, specific membrane flux increased (PACl:0.56-0.64; FeCl3: 0.71-0.76) and cake resistance decreased (PACl:0.90×10-11-0.52×10-11 m-1; FeCl3:0.47×10-11-0.28×10-11 m-1). However, when the dosage of PAM increased to 1.0 mg/L, the membrane flux decreased significantly to 0.48 while cake resistance increased to 1.55×10-11 m-1. An optimum flocculant dosage (0.4 mg/L) that caused the minimum membrane fouling was confirmed. Furthermore, the results obtained from Nanoseries Zetasizer and scanning electron microscopy (SEM) demonstrated that cake layer was the dominant fouling mechanism under different conditions and membrane pore blocking was severe with higher PAM dosage.
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| Key words: aluminium polychlorid ferric trichloride polyacrylamide ultrafiltration membrane fouling |
