| 引用本文: | 宗文俊,李增强,胡振江,孙涛,苑世剑.天然金刚石晶体的真空热化学腐蚀工艺[J].哈尔滨工业大学学报,2013,45(3):61.DOI:10.11918/j.issn.0367-6234.2013.03.011 |
| ZONG Wenjun,LI Zengqiang,HU Zhenjiang,SUN Tao,YUAN Shijian.Thermo-chemical erosion of natural diamond crystals under vacuum atmosphere[J].Journal of Harbin Institute of Technology,2013,45(3):61.DOI:10.11918/j.issn.0367-6234.2013.03.011 |
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| 摘要: |
| 为了给天然金刚石刀具的使用寿命延长提供一种全新的技术方法,提出了基于纳米氧化铜的真空热化学腐蚀新工艺,用于后处理机械刃磨工艺加工的天然金刚石晶体．实验结果表明,当真空环境温度为100 ℃时,天然金刚石晶体表面受损碳原子和纳米氧化铜发生氧化、还原反应．随着腐蚀时间的增加,天然金刚石晶体的表面粗糙度缓慢降低,呈现微弱的平坦化趋势．当真空环境温度为200 ℃时,2 h的热处理时间为最佳．此过程中天然金刚石晶体表面受损碳原子和纳米氧化铜发生氧化、还原反应,同时伴随受损碳原子的退火修复作用,因此30 nm压痕深度下的表面微硬度和弹性模量值达到最大．随着腐蚀时间增加,表面微硬度和弹性模量反而下降． |
| 关键词: 天然金刚石 纳米氧化铜 真空热化学腐蚀 退火 微硬度 |
| DOI：10.11918/j.issn.0367-6234.2013.03.011 |
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| 基金项目:国家自然科学基金资助项目(51175127);哈工大校科研创新基金资助项目(HIT.NSRIF.2009019);数控机床科技重大专项基金资助项目(2011ZX04004-031);国防基础科研基金资助项目(A0920110019)． |
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| Thermo-chemical erosion of natural diamond crystals under vacuum atmosphere |
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ZONG Wenjun1,2, LI Zengqiang1, HU Zhenjiang1, SUN Tao1, YUAN Shijian2
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(1. School of Mechatronics Engineering, Harbin Institute of Technology, 150001 Harbin, China; 2. School of Materials Science and Engineering, Harbin Institute of Technology, 150001 Harbin, China)
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| Abstract: |
| To provide a novel technique to prolong the service life of diamond cutting tools, a thermo-chemical erosion method by using nano-scale copper oxide under vacuum atmosphere was proposed to perform the post-treatment of natural diamond crystals, which had been pre-polished with mechanical lapping procedure. As indicated in the experiments, when the temperature under vacuum atmosphere was 100 ℃, the oxidation and deoxidation appeared between the damaged diamond carbon atoms on the topmost surface layer and the copper oxide powder. The surface roughness of natural diamond crystal declined slowly with the increment of erosion time, i.e. generating a weak planarization tendency. When the vacuum atmosphere temperature was 200 ℃, two hours erosion time was considered as the optimal configuration. At 30 nm indentation depth, the micro-hardness and elastic ratio of the eroded diamond crystal surface reached the maximal value. If the erosion time was larger than two hours, the micro-hardness and elastic ratio declined. |
| Key words: natural diamond nanometer copper oxide thermo-chemical erosion annealing micro hardness
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